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There seems to be a mundane explanation, according to a just published article in New Scientist.
Excerpt:
Besides, the scientists who have measured the Pioneer anomaly are smart enough to account for relativistic effects, such as changes in mass and the curvature of spacetime.
They don't need your "Mind of Man" suggestion that the speed of light (or its square) is not well measured. In fact, the value of c is known to a much greater precision (I'm guessing one part in 1012 or so.) than the anomaly, measured by the tools of better men and women than you or I.
Fred Bortz -- Science and technology books for young readers (www.fredbortz.com) and Science book reviews (www.scienceshelf.com)